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Chemistry

Acid–base titration

Analytical chemistry · Volumetric analysis

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How can a few drops of pink dye tell you exactly how much acid is in a flask?

In a titration you add a base, drop by drop, to an acid until the two have exactly cancelled each other out. You know how strong the base is, so the volume you needed tells you how much acid there was. A dye called an indicator turns pink the moment there is a tiny bit of base left over.

In an acid–base titration a solution of accurately known concentration is added from a burette until it has exactly neutralised a measured volume of the unknown. For 0.100 M HCl against 0.100 M NaOH the pH rises slowly, then leaps from about 4 to 10 within a single drop at 25.00 cm³, which an indicator such as phenolphthalein or a pH electrode detects.

Key facts

Analyte
25.0 cm³ of 0.100 mol dm⁻³ HCl
Titrant
0.100 mol dm⁻³ NaOH
Equivalence volume
25.00 cm³
pH at equivalence (25 °C)
7.00
Phenolphthalein range
pH ≈ 8.2 (colourless) → 10.0 (pink)
Burette reading precision
± 0.05 cm³

Parts you can explore (13)

In the 3D model

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