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Chemistry

Mass spectrometer (magnetic sector)

Analytical chemistry · Instrumentation

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How can you weigh a single atom — and tell two kinds of chlorine apart by a difference of two neutrons?

A mass spectrometer turns molecules into charged particles (ions), fires them down a tube, and bends their paths with a magnet. Heavier ions are harder to turn, so they swing round wider curves. By changing the magnet’s strength, the machine lets one mass at a time hit a detector and counts how many arrive.

A mass spectrometer turns molecules into gas-phase ions, accelerates them and separates them by mass-to-charge ratio, here by bending their paths in a magnetic field. Scanning the field brings each m/z in turn onto a detector, producing a spectrum that reveals isotopes, molecular masses and fragmentation patterns.

Key facts

Ionisation energy (EI)
70 eV electrons
Accelerating voltage (model)
2.00 kV
Sector radius (model)
20.0 cm
Operating pressure
≈ 10⁻⁴–10⁻⁶ Pa
³⁵Cl : ³⁷Cl natural abundance
75.8% : 24.2% (≈ 3 : 1)
Field for m/z 35 (model)
0.190 T

Parts you can explore (11)

In the 3D model

Rotate and take apart the model, follow a guided tour of what each part does and why it’s needed, change it with a live slider, and test yourself with a short quiz. Free, no sign-up.

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