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Lithium-ion battery (18650)

Electrochemistry · Energy storage

3D cutaway of the lithium-ion battery (18650) Open the interactive 3D model →

What actually moves inside your phone battery when you plug it in?

A lithium-ion battery stores energy by moving tiny charged lithium atoms (ions) from one side to the other. Charging pushes them into layers of graphite, the same stuff as pencil lead; using the battery lets them flow back. While the ions travel through the inside, electrons are forced to take the long way round through your phone, and that flow powers it.

A lithium-ion cell stores energy by moving lithium between two host materials: on charge Li⁺ ions leave a layered metal-oxide cathode and intercalate into graphite, and on discharge they return while electrons flow through the external circuit. The large difference in lithium’s chemical potential between the two electrodes gives an average cell voltage of about 3.6–3.7 V and a high energy per kilogram.

Key facts

18650 format
18 mm diameter × 65 mm long, ≈ 45–48 g
Capacity (typical 18650)
≈ 2.5–3.5 Ah
Voltage window
≈ 2.5–3.0 V empty to 4.2 V full; nominal 3.6–3.7 V
Specific energy (cell)
≈ 200–270 Wh kg⁻¹
Graphite capacity
372 mAh g⁻¹ (theoretical, LiC₆)
Cycle life
≈ 500–2000 full cycles to 80 % capacity, depending on chemistry and use

Parts you can explore (13)

In the 3D model

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