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Lead-acid car battery

Electrochemistry · Energy storage

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How does a box of lead and acid deliver enough power to spin a car engine on a frosty morning?

A car battery is six small batteries joined in a row, each making about 2 volts. Inside each one, two kinds of lead plates sit in sulfuric acid, and a chemical reaction between them pushes electrons round a circuit. Charging the battery runs that reaction backwards, so it can be used hundreds of times.

A lead-acid battery stores energy in plates of lead dioxide and spongy lead immersed in sulfuric acid; on discharge both plates turn into lead sulfate and the acid is diluted towards water. Six ≈ 2.1 V cells in series make the 12 V battery that starts almost every petrol and diesel car.

Key facts

Cell voltage (open circuit)
≈ 2.10–2.13 V charged; ≈ 1.95–2.0 V discharged
Battery voltage
12.6–12.7 V full; ≈ 11.9 V flat (open circuit, at rest)
Electrolyte
H₂SO₄, SG ≈ 1.27–1.28 charged (≈ 35–37 % by mass)
Specific energy
≈ 30–40 Wh kg⁻¹
Cranking current
≈ 400–800 A for a few seconds
Recycling rate
> 95 % of lead recovered in many countries

Parts you can explore (12)

In the 3D model

Rotate and take apart the model, follow a guided tour of what each part does and why it’s needed, change it with a live slider, and test yourself with a short quiz. Free, no sign-up.

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