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Physics

Hydrogen spectrum

Atomic physics · Bohr model and line spectra

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Why does glowing hydrogen give off just a few sharp colours instead of a whole rainbow?

A hydrogen atom is one electron held by one proton, and the electron is only allowed to have certain fixed amounts of energy. When it drops from a higher level to a lower one, it gives out a tiny packet of light (a photon) whose colour depends on the size of the drop. Only a few drop sizes are possible, so only a few colours appear.

Excited hydrogen atoms emit light only at sharp, discrete wavelengths because the electron can occupy only certain energy levels, E_n = −13.6 eV/n², and each photon carries away exactly the difference between two levels. The Rydberg formula 1/λ = R_H(1/n_f² − 1/n_i²) predicts every line, grouping them into the ultraviolet Lyman, visible Balmer and infrared Paschen series.

Key facts

Ground-state energy
−13.6 eV (ionisation energy 13.6 eV)
Energy levels
E_n = −13.6 eV / n²
Rydberg constant for hydrogen
R_H = 1.09678 × 10⁷ m⁻¹
Visible Balmer lines
656, 486, 434, 410 nm (vacuum)
Bohr radius
a₀ = 0.0529 nm; r_n = n²a₀
Model scale
Orbit radii drawn ∝ n, not n²; energy ladder to scale

Parts you can explore (12)

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