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Chemistry

Haber–Bosch process

Industrial chemistry · Equilibrium & catalysis

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How does half the food on Earth depend on pulling nitrogen out of thin air?

Plants need nitrogen to grow, and the air is 78% nitrogen — but it is locked in molecules too tough for crops to use. The Haber–Bosch process squeezes nitrogen and hydrogen together over hot iron to make ammonia, which becomes fertiliser. Any gas that does not react is sent round again, so almost nothing is wasted.

The Haber–Bosch process combines nitrogen from air with hydrogen over an iron catalyst at about 400–500 °C and 150–300 bar to make ammonia, the starting point of almost all synthetic fertiliser. Because the reaction is exothermic and reduces the number of gas molecules, plants balance equilibrium yield against rate and recycle the unreacted gas around a loop.

Key facts

Reaction
N₂ + 3H₂ ⇌ 2NH₃, ΔH° = −92 kJ/mol
Typical conditions
400–500 °C, 150–300 bar
Catalyst
Fe (from Fe₃O₄) promoted with K₂O, Al₂O₃, CaO
Conversion per pass
≈ 15–25 %
Overall conversion (with recycle)
> 97 %
World production
≈ 180 million tonnes NH₃ per year

Parts you can explore (15)

In the 3D model

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