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Vanadium redox flow battery

Electrochemistry · Grid energy storage

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Could you store a town’s electricity in giant tanks of coloured liquid?

A flow battery keeps its energy in two big tanks of liquid instead of inside sealed cells. Pumps push the liquids through a stack of thin cells, where electricity changes the dissolved metal (vanadium) to store energy, and changing it back gives the energy out again. To store more energy you simply use bigger tanks.

A vanadium redox flow battery stores energy in two tanks of vanadium electrolyte that are pumped through a stack of cells, where the vanadium ions are oxidised and reduced on carbon-felt electrodes separated by an ion-exchange membrane. Because the active material is dissolved rather than built into the electrodes, energy capacity (tank volume) and power (stack area) are sized independently, which suits long-duration grid storage.

Key facts

Standard cell potential
E° ≈ 1.26 V; ≈ 1.4 V at 50 % SOC in practice
Electrolyte
1.5–2 M vanadium in 2–5 M H₂SO₄
Energy density
≈ 15–25 Wh per litre of electrolyte
Round-trip efficiency
≈ 65–80 % (AC to AC, including pumps)
Cycle life
> 10,000 cycles; design life 20+ years
Operating temperature
≈ 10–40 °C

Parts you can explore (12)

In the 3D model

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